Structure database (LMSD)

  MDLMOL files can be opened in various drawing programs. In ChemDraw, open as filetype "MDL Molfile".
(One of 3 possible positional isomers) Display all isomers
LM IDLMGL03010054
Common NameTG(16:0/16:0/18:3(9Z,12Z,15Z))[iso3]
Systematic Name1,2-dihexadecanoyl-3-(9Z,12Z,15Z-octadecatrienoyl)-sn-glycerol
SynonymsTG(16:0/16:0/18:3)[iso3]; TG(50:3); TG(16:0_16:0_18:3)
Exact Mass
828.7207 (neutral)    Calculate m/z:
FormulaC53H96O6
CategoryGlycerolipids [GL]
Main ClassTriradylglycerols [GL03]
Sub ClassTriacylglycerols [GL0301]
PubChem CID25240358
HMDB IDHMDB10417
SWISSLIPIDS IDSLM:000144992
InChIKeyWLFXGZDFDKIDIL-AVVZNEQPSA-N  Show lipids differing only in stereochemistry/bond geometry
InChIInChI=1S/C53H96O6/c1-4-7-10-13-16-19-22-25-26-29-31-34-37-40-43-46-52(55)58-49-5
0(59-53(56)47-44-41-38-35-32-28-24-21-18-15-12-9-6-3)48-57-51(54)45-42-39-36-33-
30-27-23-20-17-14-11-8-5-2/h7,10,16,19,25-26,50H,4-6,8-9,11-15,17-18,20-24,27-49
H2,1-3H3/b10-7-,19-16-,26-25-/t50-/m1/s1
SMILESC(OC(=O)CCCCCCC/C=C\C/C=C\C/C=C\CC)[C@]([H])(OC(CCCCCCCCCCCCCCC)=O)COC(CCCCCCCCC
CCCCCC)=O
StatusActive (generated by computational methods)
Calculated physicochemical properties (?):
 Heavy Atoms59Rings0Aromatic Rings0Rotatable Bonds49
 van der Waals
Molecular Volume
962.36Topological Polar
Surface Area
78.90Hydrogen
Bond Donors
0Hydrogen
Bond Acceptors
6
 logP17.39Molar
Refractivity
253.18    
LIPID MAPS abbreviations for glycerolipids (GL)

The LIPID MAPS glycerolipid abbreviations (MG,DG,TG) are used here to refer to species with one, two or three radyl side-chains, respectively, where the structures of the side chains are indicated within parentheses in the 'Prefix(sn1/sn2/sn3)' format (e.g. TG(16:0/18:1(9Z)/18:0). Acyl chains are assumed by default. The alkyl ether linkage is represented by the 'O-' prefix, e.g. DG(O-16:0/18:1(9Z)/0:0), whereas the 1Z-alkenyl ether (Plasmalogen) linkage is represented by the 'P-' prefix, e.g. and DG(P-14:0/18:1(9Z)/0:0).

For Diradylglycerols and Triradylglycerols, it is not always possible to experimentally determine the exact position of radyl groups on the glycerol group. For Diradylglycerols with two different radyl groups, two different structural isomers exist. For Triradylglycerols with three different radyl groups, six different isomers exist.

Instead of drawing all possible structural isomers explicitly for Diradylglycerols and Triradylglycerols, the LIPID MAPS abbreviation scheme supports the isomeric specification. A suffix containing 'iso' along with the number of possible isomers is appended to the abbreviation (e.g. [iso2],[iso6]) and a single unique LM_ID is assigned. The structure assigned to the LM_ID corresponds to the radyl substitution shown in the abbreviation. An option is provided to display the other isomers in the group.

The [rac] designation refers to racemic mixtures due to substitution at the sn1 and sn3 positions of glycerol.