Commonly occurring product ions for PC(11:0/24:0) (View full structure)

m/zIon DescriptionStructure (click to enlarge)
810.5785Precursor ion [M.chloride]-
760.5862Loss of CH3 and chloride from precursor ion
689.5127Loss of choline and chloride from precursor ion
592.4348Loss of sn1 acyl chain as ketene (RCH=C=O), CH3 and chloride from precursor ion
574.4242Neutral loss of sn1 RCOOH group, loss of CH3 and chloride from precursor ion
410.2313Loss of sn2 acyl chain as ketene (RCH=C=O), CH3 and chloride from precursor ion
392.2208Neutral loss of sn2 RCOOH group, loss of CH3 and chloride from precursor ion
367.3582sn2 RCOO- ion
224.0693Glycerophosphocholine with loss of CH3 and H2O
185.1547sn1 RCOO- ion
168.0431Phosphocholine with loss of CH3
152.9958Glycerol-3-phosphate ion with loss of H2O
96.9696H2PO4- ion (from phosphate)
78.9591PO3- ion (from phosphate)
Note: Structures of product ions may represent one of a number of possible isobaric molecules in some cases