Commonly occurring product ions for PC(O-16:0/18:1(9Z)) (View full structure)

m/zIon DescriptionStructure (click to enlarge)
745.5991Precursor ion [M+]-
730.5756Loss of CH3 and from precursor ion
659.5021Loss of choline and from precursor ion
466.3303Loss of sn2 acyl chain as ketene (RCH=C=O), CH3 and from precursor ion
448.3197Neutral loss of sn2 RCOOH group, loss of CH3 and from precursor ion
377.2462Loss of choline, and neutral loss of sn2 RCOOH group from precursor ion
281.2486sn2 RCOO- ion
224.0693Glycerophosphocholine with loss of CH3 and H2O
168.0431Phosphocholine with loss of CH3
152.9958Glycerol-3-phosphate ion with loss of H2O
96.9696H2PO4- ion (from phosphate)
78.9591PO3- ion (from phosphate)
Note: Structures of product ions may represent one of a number of possible isobaric molecules in some cases