Commonly occurring product ions for PG(12:0/18:2(9Z,12Z)) (View full structure)
| m/z | Ion Description | Structure (click to enlarge) |
|---|---|---|
| 689.4399 | Precursor ion [M-H]- |  |
| 615.4031 | Loss of glycerol from precursor ion |  |
| 507.2729 | Loss of sn1 acyl chain as ketene (RCH=C=O) from [M-H]- |  |
| 489.2623 | Neutral loss of sn1 RCOOH group from [M-H]- |  |
| 433.2361 | Loss of sn1 acyl chain as ketene (RCH=C=O) and glycerol from [M-H]- |  |
| 427.2103 | Loss of sn2 acyl chain as ketene (RCH=C=O) from [M-H]- |  |
| 415.2255 | Neutral loss of sn1 RCOOH group and glycerol from [M-H]- |  |
| 409.1997 | Neutral loss of sn2 RCOOH group from [M-H]- |  |
| 353.1735 | Loss of sn2 acyl chain as ketene (RCH=C=O) and glycerol from [M-H]- |  |
| 335.1629 | Neutral loss of sn2 RCOOH group and glycerol from [M-H]- |  |
| 279.2330 | sn2 RCOO- ion |  |
| 245.0432 | Glycerophosphoglycerol ion |  |
| 227.0326 | Glycerophosphoglycerol ion -H2O |  |
| 209.0221 | Glycerophosphoglycerol ion -2H2O |  |
| 199.1704 | sn1 RCOO- ion |  |
| 152.9958 | Glycerol-3-phosphate ion with loss of H2O |  |
| 96.9696 | H2PO4- ion (from phosphate) |  |
| 78.9591 | PO3- ion (from phosphate) |  |