Structure Database (LMSD)

Common Name
6-keto PGE1
Systematic Name
6,9-dioxo-11R,15S-dihydroxy-13E-prostenoic acid
Synonyms
  • 6-keto Prostaglandin E1
LM ID
LMFA03010012
Formula
Exact Mass
Calculate m/z
368.21989
Sum Composition
Status
Curated


Classification

Biological Context

6-keto PGE1 is a metabolite isolated after the incubation of PGI2 with rabbit liver microsomes.1 However, it is not produced in appreciable amounts following IV infusion of PGI2 in humans.2 6-keto PGE1 is equipotent with PGI2 as a vasodilator; in most other aspects its activity resembles PGE1.3

This information has been provided by Cayman Chemical

References

2. Wong, P.Y.K., Malik, K.U., Desiderio, D.M., et al. Hepatic metabolism of prostacyclin (PGI2) in the rabbit: Formation of a potent novel inhibitor of platelet aggregation. Biochem. Biophys. Res. Commun. 93(2), 486-494 (1980).
3. Jackson, E.K., Goodman, R.P., Fitzgerald, G.A., et al. Assessment of the extent to which exogenous prostaglandin I2 is converted to 6-keto-prostaglandin E1 in human subjects. J. Pharmacol. Exp. Ther. 221(1), 183-187 (1982).

String Representations

InChiKey (Click to copy)
ROUDCKODIMKLNO-CTBSXBMHSA-N
InChi (Click to copy)
InChI=1S/C20H32O6/c1-2-3-4-7-14(21)10-11-16-17(19(24)13-18(16)23)12-15(22)8-5-6-9-20(25)26/h10-11,14,16-18,21,23H,2-9,12-13H2,1H3,(H,25,26)/b11-10+/t14-,16+,17+,18+/m0/s1
SMILES (Click to copy)
[C@H]1(/C=C/[C@@H](O)CCCCC)[C@H](O)CC(=O)[C@@H]1CC(=O)CCCCC(=O)O

Other Databases

KEGG ID
HMDB ID
CHEBI ID
LIPIDBANK ID
XPR1430
PubChem CID
Cayman ID

Calculated Physicochemical Properties

Heavy Atoms 26
Rings 1
Aromatic Rings 0
Rotatable Bonds 13
Van der Waals Molecular Volume 384.38
Topological Polar Surface Area 111.90
Hydrogen Bond Donors 3
Hydrogen Bond Acceptors 6
logP 3.23
Molar Refractivity 98.65

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Updated at
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