Structure Database (LMSD)

HO O OH O O P OH O OH P O O O O O HO O HO O O NH O O HO NH O O O
Common Name
Rhodobacter capsulatus Lipid A
Systematic Name
Synonyms
LM ID
LMSL01050003
Formula
C74H134N2O24P2
Exact Mass
Calculate m/z
1496.880184
Status
Active
Show lipids differing only in stereochemistry/bond geometry

Main

Classification

Category
Main Class
Sub Class
Saccharolipids [SL]
Acylaminosugars [SL01]
Pentaacylaminosugars [SL0105]

String Representations

InChiKey (Click to copy)
SNMOHKBRTYQJQE-ORTWDDADSA-N
InChi (Click to copy)
InChI=1S/C74H134N2O24P2/c1-6-11-16-21-25-28-32-37-40-45-56(78)50-62(81)75-67-71(97-65(84)52-58(80)47-42-36-31-24-19-14-9-4)69(86)61(96-74(67)100-102(90,91)92)55-93-73-68(76-63(82)51-57(79)46-41-38-33-29-26-22-17-12-7-2)72(70(60(54-77)95-73)99-101(87,88)89)98-66(85)53-59(48-43-35-20-15-10-5)94-64(83)49-44-39-34-30-27-23-18-13-8-3/h30,34,58-61,67-74,77,80,86H,6-29,31-33,35-55H2,1-5H3,(H,75,81)(H,76,82)(H2,87,88,89)(H2,90,91,92)/b34-30-/t58-,59-,60-,61-,67-,68-,69-,70-,71-,72-,73-,74-/m1/s1
SMILES (Click to copy)
O(P(O)(=O)O)[C@@H]1[C@H](NC(=O)CC(=O)CCCCCCCCCCC)[C@@H](OC(=O)C[C@H](O)CCCCCCCCC)[C@H](O)[C@@H](CO[C@H]2[C@H](NC(=O)CC(=O)CCCCCCCCCCC)[C@@H](OC(=O)C[C@H](OC(=O)CCC/C=C\CCCCCC)CCCCCCC)[C@H](OP(O)(O)=O)[C@@H](CO)O2)O1

References

Taxonomy Information

Curated from
NCBI taxonomy class
Reference
Rhodobacter capsulatus (#1061)
Alphaproteobacteria (#28211)
The Role of Carbohydrates in the Lipopolysaccharide (LPS)/Toll-Like Receptor 4 (TLR4) Signalling.,
Int J Mol Sci, 2017
Pubmed ID: 29099761

Other Databases

PubChem CID
171121059

Calculated Physicochemical Properties

Heavy Atoms 102
Rings 2
Aromatic Rings 0
Rotatable Bonds 67
Van der Waals Molecular Volume 1515.54
Topological Polar Surface Area 397.28
Hydrogen Bond Donors 9
Hydrogen Bond Acceptors 26
logP 17.89
Molar Refractivity 392.40

Admin

Created at
29th Jun 2020
Updated at
29th Jun 2020