Common Name
LM ID
Instrument
Adduct / Ion
Submitter
11-deoxycorticosterone
Thermo Quantum triple quarupole MS interfaced with Trace GC Ultra (Thermo)
[M.]+
Ruth Andrew
[{"mz":447.6532898,"intensity":0.975885487},{"mz":412.3201765,"intensity":62.61310217},{"mz":464.1737991,"intensity":305.8361816},{"mz":386.7723216,"intensity":325.9305664},{"mz":305.3019559,"intensity":358.718396},{"mz":413.8711275,"intensity":372.4748047},{"mz":462.5455933,"intensity":824.8100586},{"mz":427.1755576,"intensity":863.8337227},{"mz":481.4500169,"intensity":869.4951521},{"mz":398.3356359,"intensity":962.5953369},{"mz":406.2401718,"intensity":982.7459961},{"mz":477.8572494,"intensity":1070.095667},{"mz":423.2400178,"intensity":1099.405157},{"mz":445.7683048,"intensity":1169.767213},{"mz":420.3088692,"intensity":1217.884595},{"mz":470.5787489,"intensity":1408.784637},{"mz":461.231032,"intensity":1503.289506},{"mz":403.1918047,"intensity":1676.323138},{"mz":478.7613126,"intensity":1687.240063},{"mz":422.4673695,"intensity":1962.442883},{"mz":479.5485323,"intensity":2000.213899},{"mz":437.4396376,"intensity":2041.671704},{"mz":438.0732117,"intensity":2109.283008},{"mz":332.3269887,"intensity":2134.651416},{"mz":409.0012351,"intensity":2156.170728},{"mz":240.1003773,"intensity":2163.860693},{"mz":235.6745464,"intensity":2255.047998},{"mz":456.5662399,"intensity":2267.733569},{"mz":483.1726403,"intensity":2501.309827},{"mz":454.9831979,"intensity":2652.351489},{"mz":432.4760044,"intensity":2677.549719},{"mz":476.2019877,"intensity":2833.242599},{"mz":431.80563,"intensity":2834.93493},{"mz":423.8703149,"intensity":2925.086182},{"mz":426.5320528,"intensity":2979.653411},{"mz":409.7624258,"intensity":3001.586145},{"mz":476.9717001,"intensity":3115.893213},{"mz":482.4157978,"intensity":3157.906036},{"mz":457.2160511,"intensity":3158.458731},{"mz":306.6515774,"intensity":3191.069334},{"mz":436.2065253,"intensity":3234.066113},{"mz":444.7724719,"intensity":3589.872742},{"mz":232.0473123,"intensity":3785.215625},{"mz":471.5395513,"intensity":3803.196246},{"mz":467.323708,"intensity":4025.445313},{"mz":448.1547056,"intensity":4259.10708},{"mz":440.5239271,"intensity":4544.309372},{"mz":416.3030795,"intensity":4569.409692},{"mz":433.5090027,"intensity":4789.484766},{"mz":457.8811325,"intensity":4798.221875},{"mz":425.3192999,"intensity":4808.142969},{"mz":401.7280631,"intensity":5376.940039},{"mz":460.6053011,"intensity":5496.665326},{"mz":326.9108776,"intensity":5522.792578},{"mz":411.5151266,"intensity":5771.743842},{"mz":413.1705674,"intensity":5937.819434},{"mz":459.3079796,"intensity":5960.782324},{"mz":302.5094261,"intensity":6014.587708},{"mz":447.1499365,"intensity":6042.148975},{"mz":465.0641455,"intensity":6049.919745},{"mz":473.8058355,"intensity":6105.971973},{"mz":330.0696729,"intensity":6119.37273},{"mz":462.0280668,"intensity":6138.101462},{"mz":463.5025877,"intensity":6437.422616},{"mz":453.5808972,"intensity":6459.649023},{"mz":410.591097,"intensity":6476.84668},{"mz":441.3766203,"intensity":6544.832129},{"mz":406.9253131,"intensity":6794.416956},{"mz":459.8175871,"intensity":6798.783984},{"mz":424.5768936,"intensity":6841.850964},{"mz":439.305951,"intensity":6884.825684},{"mz":316.834952,"intensity":7407.272168},{"mz":345.9880066,"intensity":7444.279688},{"mz":421.1636782,"intensity":7786.78584},{"mz":442.5640136,"intensity":7793.737451},{"mz":183.565871,"intensity":7888.455957},{"mz":428.5077489,"intensity":8051.482769},{"mz":365.2119997,"intensity":8404.622238},{"mz":419.1031034,"intensity":8514.430393},{"mz":430.4990746,"intensity":8562.309327},{"mz":384.2990615,"intensity":8907.938672},{"mz":376.0162048,"intensity":9077.09375},{"mz":465.8033818,"intensity":9196.417285},{"mz":399.5578843,"intensity":9719.774695},{"mz":292.2906073,"intensity":9765.938989},{"mz":402.4207687,"intensity":9870.836029},{"mz":186.0938065,"intensity":9872.134473},{"mz":393.8552615,"intensity":10333.20544},{"mz":279.3949377,"intensity":10371.77598},{"mz":345.0105482,"intensity":10571.30686},{"mz":388.1239829,"intensity":10589.69492},{"mz":366.519043,"intensity":10776.79766},{"mz":414.9174443,"intensity":10884.2033},{"mz":322.3979354,"intensity":11205.92459},{"mz":455.7236383,"intensity":11236.68947},{"mz":403.7180484,"intensity":11379.80938},{"mz":295.8479004,"intensity":11435.30938},{"mz":323.7734254,"intensity":11477.37732},{"mz":299.8750787,"intensity":11729.66094},{"mz":367.1207894,"intensity":11860.3726},{"mz":318.9111171,"intensity":12586.32542},{"mz":325.2265403,"intensity":12830.27015},{"mz":339.7275524,"intensity":12835.68402},{"mz":245.1016034,"intensity":12872.4041},{"mz":338.1098008,"intensity":13021.69283},{"mz":417.4150011,"intensity":13243.3243},{"mz":369.8984969,"intensity":13479.58677},{"mz":387.4112045,"intensity":13511.23411},{"mz":392.1631232,"intensity":14515.2896},{"mz":468.7921051,"intensity":15196.25283},{"mz":405.0797861,"intensity":15239.95011},{"mz":407.9835455,"intensity":15275.15347},{"mz":181.9203583,"intensity":15584.91104},{"mz":379.1465331,"intensity":16083.64004},{"mz":234.2012662,"intensity":16200.91641},{"mz":218.1268616,"intensity":16249.03281},{"mz":370.9373237,"intensity":16377.52939},{"mz":337.4047184,"intensity":16447.2873},{"mz":328.5417312,"intensity":16891.26023},{"mz":434.9678574,"intensity":17048.40376},{"mz":452.5169626,"intensity":17152.98461},{"mz":364.6352233,"intensity":17443.4832},{"mz":378.2741699,"intensity":17514.52417},{"mz":396.4122794,"intensity":17628.28713},{"mz":243.3825898,"intensity":17670.52009},{"mz":266.6836257,"intensity":17819.86094},{"mz":393.044714,"intensity":17851.64469},{"mz":400.6463154,"intensity":18131.94152},{"mz":237.1030611,"intensity":18691.02578},{"mz":386.2412011,"intensity":18762.8709},{"mz":338.9562723,"intensity":18818.58843},{"mz":394.5288029,"intensity":18889.31794},{"mz":322.9754236,"intensity":19069.49902},{"mz":379.949566,"intensity":19184.05977},{"mz":333.8725113,"intensity":19260.01875},{"mz":222.688776,"intensity":19263.88816},{"mz":180.2944031,"intensity":19864.09219},{"mz":385.4212317,"intensity":19884.59177},{"mz":296.9524832,"intensity":20088.31289},{"mz":342.3746062,"intensity":20403.08901},{"mz":397.7888619,"intensity":20790.47812},{"mz":247.0389702,"intensity":21066.78049},{"mz":254.0181274,"intensity":21527.17656},{"mz":390.9630231,"intensity":21770.26047},{"mz":219.946246,"intensity":21841.32578},{"mz":371.6218682,"intensity":21899.22923},{"mz":389.2214708,"intensity":22435.28872},{"mz":350.4210457,"intensity":22517.84126},{"mz":330.9925132,"intensity":23339.91548},{"mz":336.3318055,"intensity":23481.78402},{"mz":327.5992544,"intensity":24220.75234},{"mz":326.1320516,"intensity":24659.47791},{"mz":192.6493803,"intensity":24849.77256},{"mz":212.3566887,"intensity":25919.12031},{"mz":357.8347653,"intensity":26015.87777},{"mz":355.4227382,"intensity":26947.76641},{"mz":353.7218343,"intensity":27149.90652},{"mz":344.2817926,"intensity":27727.59976},{"mz":319.7268982,"intensity":27910.45032},{"mz":249.9220358,"intensity":28534.32903},{"mz":324.5383054,"intensity":29200.27065},{"mz":329.3455919,"intensity":29529.17505},{"mz":360.5194718,"intensity":29873.28831},{"mz":272.9579822,"intensity":29904.96836},{"mz":343.1868749,"intensity":30058.73486},{"mz":381.3160448,"intensity":30079.98411},{"mz":369.3408044,"intensity":30905.96369},{"mz":375.3882938,"intensity":31008.33628},{"mz":311.4238022,"intensity":31277.49773},{"mz":251.4465451,"intensity":31455.95664},{"mz":450.9646513,"intensity":32098.40243},{"mz":341.2854492,"intensity":32389.64906},{"mz":260.8636596,"intensity":33046.47917},{"mz":334.9943217,"intensity":33766.58191},{"mz":331.569288,"intensity":34253.18281},{"mz":264.3459647,"intensity":35129.37812},{"mz":354.8021223,"intensity":35197.12959},{"mz":372.6710965,"intensity":36465.08091},{"mz":365.9106725,"intensity":37011.64238},{"mz":250.6944696,"intensity":37026.25896},{"mz":333.1159163,"intensity":37546.25769},{"mz":312.3135092,"intensity":38002.23516},{"mz":352.7775792,"intensity":38399.98354},{"mz":315.0429439,"intensity":39362.40957},{"mz":295.333761,"intensity":39531.31469},{"mz":383.3930633,"intensity":39590.42158},{"mz":363.9746426,"intensity":40709.79414},{"mz":377.13002,"intensity":41570.78145},{"mz":263.6842323,"intensity":42840.09989},{"mz":252.7564281,"intensity":47249.60059},{"mz":367.9883388,"intensity":47806.83404},{"mz":237.8917881,"intensity":47831.17769},{"mz":277.4277692,"intensity":48741.07188},{"mz":449.5719069,"intensity":49311.25179},{"mz":294.6285606,"intensity":49837.08713},{"mz":293.8486036,"intensity":50087.54846},{"mz":268.3529178,"intensity":50862.46563},{"mz":356.816571,"intensity":51281.38541},{"mz":190.1526796,"intensity":51325.53037},{"mz":317.9859122,"intensity":51362.19771},{"mz":361.2168539,"intensity":51788.63906},{"mz":310.4738288,"intensity":51938.04418},{"mz":226.0955831,"intensity":52202.77839},{"mz":301.74051,"intensity":52801.50575},{"mz":194.8768778,"intensity":53123.34922},{"mz":275.9620867,"intensity":53147.5502},{"mz":274.5794624,"intensity":53521.47974},{"mz":194.2763636,"intensity":53616.1625},{"mz":321.010525,"intensity":53940.97739},{"mz":195.5575744,"intensity":53967.48281},{"mz":316.1748345,"intensity":54171.04199},{"mz":191.7880564,"intensity":54471.6498},{"mz":184.4099044,"intensity":54749.32521},{"mz":362.4421736,"intensity":55384.99805},{"mz":197.8474238,"intensity":55704.90146},{"mz":247.6807492,"intensity":56671.76387},{"mz":209.1564577,"intensity":58469.36157},{"mz":185.5340685,"intensity":59632.29688},{"mz":348.4120447,"intensity":60958.91593},{"mz":313.3772789,"intensity":61258.65723},{"mz":225.0462137,"intensity":62725.27651},{"mz":261.3926945,"intensity":62770.85313},{"mz":253.3095944,"intensity":63765.2375},{"mz":307.4849768,"intensity":66640.61891},{"mz":275.3105568,"intensity":66762.58303},{"mz":309.0542769,"intensity":67855.92607},{"mz":374.402774,"intensity":68240.11709},{"mz":208.3906265,"intensity":69680.4207},{"mz":210.194852,"intensity":70080.2165},{"mz":236.489394,"intensity":70172.07188},{"mz":300.8019631,"intensity":73381.07025},{"mz":304.4715559,"intensity":75464.37109},{"mz":222.0543154,"intensity":76474.45234},{"mz":265.2787553,"intensity":76717.51191},{"mz":239.2025021,"intensity":77971.05754},{"mz":262.5292911,"intensity":78593.47476},{"mz":220.8030179,"intensity":79387.92557},{"mz":276.856658,"intensity":79416.68477},{"mz":223.6164431,"intensity":80958.70596},{"mz":248.9467181,"intensity":81884.4574},{"mz":351.5505601,"intensity":82348.90371},{"mz":293.1429362,"intensity":82706.43125},{"mz":203.7759749,"intensity":82899.95625},{"mz":205.5752325,"intensity":83415.39708},{"mz":193.1923184,"intensity":84619.39746},{"mz":303.1512221,"intensity":84978.89531},{"mz":267.3681494,"intensity":85003.44888},{"mz":297.8983571,"intensity":85107.12053},{"mz":306.0006095,"intensity":85432.54766},{"mz":296.4074235,"intensity":89740.3083},{"mz":278.4622513,"intensity":97765.81306},{"mz":349.5150466,"intensity":98034.27375},{"mz":299.3150729,"intensity":100965.5789},{"mz":204.6746652,"intensity":102515.7519},{"mz":245.6882571,"intensity":102907.3838},{"mz":234.9255021,"intensity":103344.9243},{"mz":233.2838844,"intensity":104340.9257},{"mz":279.9524272,"intensity":105851.7053},{"mz":281.2564549,"intensity":109008.8312},{"mz":206.9703672,"intensity":112163.975},{"mz":211.2825104,"intensity":113063.9352},{"mz":359.3359161,"intensity":114728.7549},{"mz":219.3224741,"intensity":115937.7903},{"mz":191.0369948,"intensity":122742.5614},{"mz":231.541166,"intensity":125151.2872},{"mz":179.6674737,"intensity":125384.9705},{"mz":181.1857542,"intensity":126693.928},{"mz":182.9608304,"intensity":133213.1339},{"mz":196.9367682,"intensity":137616.2363},{"mz":291.7229849,"intensity":137676.6892},{"mz":273.6760544,"intensity":141531.9354},{"mz":272.0812925,"intensity":141689.6322},{"mz":259.5621388,"intensity":149091.7117},{"mz":244.051233,"intensity":150869.1823},{"mz":288.634704,"intensity":157784.918},{"mz":217.5108078,"intensity":158782.0699},{"mz":184.9888805,"intensity":162986.6557},{"mz":290.1927399,"intensity":174616.1045},{"mz":287.1038227,"intensity":188289.0063},{"mz":347.745946,"intensity":198030.1686},{"mz":189.3926578,"intensity":220635.5469},{"mz":200.1705395,"intensity":248379.0076},{"mz":242.7116163,"intensity":266407.9931},{"mz":188.3223363,"intensity":270891.5563},{"mz":199.3162645,"intensity":271880.3352},{"mz":228.797935,"intensity":274440.9202},{"mz":227.3443671,"intensity":275929.6625},{"mz":230.2254795,"intensity":283111.9684},{"mz":214.7686058,"intensity":296589.442},{"mz":241.2276482,"intensity":298559.4429},{"mz":213.2774504,"intensity":308194.6076},{"mz":283.1858049,"intensity":318226.1743},{"mz":216.1894052,"intensity":319326.8367},{"mz":255.207589,"intensity":323914.7527},{"mz":202.6914627,"intensity":333435.3061},{"mz":285.5479496,"intensity":354022.0708},{"mz":258.0877926,"intensity":358048.0253},{"mz":270.5014086,"intensity":408212.0281},{"mz":256.470384,"intensity":426676.5536},{"mz":187.1448824,"intensity":442221.9199},{"mz":346.8825007,"intensity":525667.472},{"mz":201.1940588,"intensity":566846.9164},{"mz":284.3397571,"intensity":887916.4859},{"mz":269.3208002,"intensity":1193994.806}]
Structure
Common name
11-deoxycorticosterone
LMID
Systematic name
21-hydroxypregn-4-ene-3,20-dione
m/z
460
Adduct / Ion
[M.]+
Charge
1
Ion source
EI
Instrument
Thermo Quantum triple quarupole MS interfaced with Trace GC Ultra (Thermo)
Resolution
N/A
For high resolution data only
Ion mode
Positive
Collision Energy (CE)
N/A
Column
DB-17ms (30m x 0.25 mm, 0.25 um, Agilent)
Mobile phase A
Helium
Mobile phase B
N/A
Retention time (min)
15.27
Amount injected
10 ng in 1 uL
Injector type
PTV
Source temperature
280 °C
DOI for method
Date acquired
May 2018
Submitters
Ruth Andrew
Source of standard
Steraloids