Commonly occurring product ions for PC(18:1(11Z)/22:4(7Z,10Z,13Z,16Z))) (View full structure)

m/zIon DescriptionStructure (click to enlarge)
870.5785Precursor ion [M.chloride]-
820.5862Loss of CH3 and chloride from precursor ion
749.5127Loss of choline and chloride from precursor ion
556.3409Loss of sn1 acyl chain as ketene (RCH=C=O), CH3 and chloride from precursor ion
538.3303Neutral loss of sn1 RCOOH group, loss of CH3 and chloride from precursor ion
506.3252Loss of sn2 acyl chain as ketene (RCH=C=O), CH3 and chloride from precursor ion
488.3147Neutral loss of sn2 RCOOH group, loss of CH3 and chloride from precursor ion
331.2643sn2 RCOO- ion
287.2744Loss of CO2 from sn2 RCOO- ion (PUFA)
281.2486sn1 RCOO- ion
224.0693Glycerophosphocholine with loss of CH3 and H2O
168.0431Phosphocholine with loss of CH3
152.9958Glycerol-3-phosphate ion with loss of H2O
96.9696H2PO4- ion (from phosphate)
78.9591PO3- ion (from phosphate)
Note: Structures of product ions may represent one of a number of possible isobaric molecules in some cases