Commonly occurring product ions for PI(O-22:1(11Z)/24:0) (View full structure)

m/zIon DescriptionStructure (click to enlarge)
989.7427Precursor ion [M-H]-
827.6899Loss of inositol from [M-H]-
639.3879Loss of sn2 acyl chain as ketene (RCH=C=O) from [M-H]-
621.3773Neutral loss of sn2 RCOOH group from [M-H]-
477.3351Loss of sn2 acyl chain as ketene (RCH=C=O) and inositol from [M-H]-
459.3245Neutral loss of sn2 RCOOH group and inositol from [M-H]-
367.3582sn2 RCOO- ion
315.0487Glycerophosphoinositol -H2O
297.0381Glycerophosphoinositol -2H2O
259.0225Inositol phosphate ion
241.0119Inositol phosphate ion - H2O
223.0013Inositol phosphate ion - 2 H2O
152.9958Glycerol-3-phosphate ion with loss of H2O
96.9696H2PO4- ion (from phosphate)
78.9591PO3- ion (from phosphate)
Note: Structures of product ions may represent one of a number of possible isobaric molecules in some cases