Commonly occurring product ions for PS(33:0/24:4(5Z,8Z,11Z,14Z)) (View full structure)

m/zIon DescriptionStructure (click to enlarge)
1076.8264Precursor ion [M-H]-
989.7944Loss of serine from precursor ion
647.5021Loss of sn2 acyl chain as ketene (RCH=C=O) and serine from [M-H]-
629.4916Neutral loss of sn2 RCOOH group and serine from [M-H]-
513.2987Loss of sn1 acyl chain as ketene (RCH=C=O) and serine from [M-H]-
495.2881Neutral loss of sn1 RCOOH group and serine from [M-H]-
493.4990sn1 RCOO- ion
359.2956sn2 RCOO- ion
315.3057Loss of CO2 from sn2 RCOO- ion (PUFA)
152.9958Glycerol-3-phosphate ion with loss of H2O
96.9696H2PO4- ion (from phosphate)
78.9591PO3- ion (from phosphate)
Note: Structures of product ions may represent one of a number of possible isobaric molecules in some cases