Commonly occurring product ions for PA(18:3(9Z,12Z,15Z)/14:1(9Z))) (View full structure)

m/zIon DescriptionStructure (click to enlarge)
639.4031Precursor ion [M-H]-
431.2204Loss of sn2 acyl chain as ketene (RCH=C=O) from [M-H]-
413.2099Neutral loss of sn2 RCOOH group from [M-H]-
379.1891Loss of sn1 acyl chain as ketene (RCH=C=O) from [M-H]-
361.1786Neutral loss of sn1 RCOOH group from [M-H]-
277.2173sn1 RCOO- ion
225.1860sn2 RCOO- ion
171.0064Glycerol-3-phosphate ion
152.9958Glycerol-3-phosphate ion with loss of H2O
96.9696H2PO4- ion (from phosphate)
78.9591PO3- ion (from phosphate)
Note: Structures of product ions may represent one of a number of possible isobaric molecules in some cases