Commonly occurring product ions for PA(21:0/22:4(7Z,10Z,13Z,16Z))) (View full structure)
m/z
Ion Description
Structure (click to enlarge)
793.5753
Precursor ion [M-H]-
485.2674
Loss of sn1 acyl chain as ketene (RCH=C=O) from [M-H]-
479.3143
Loss of sn2 acyl chain as ketene (RCH=C=O) from [M-H]-
467.2568
Neutral loss of sn1 RCOOH group from [M-H]-
461.3038
Neutral loss of sn2 RCOOH group from [M-H]-
331.2643
sn2 RCOO- ion
325.3112
sn1 RCOO- ion
287.2744
Loss of CO2 from sn2 RCOO- ion (PUFA)
171.0064
Glycerol-3-phosphate ion
152.9958
Glycerol-3-phosphate ion with loss of H2O
96.9696
H2PO4- ion (from phosphate)
78.9591
PO3- ion (from phosphate)
Note: Structures of product ions may represent one of a number of possible isobaric molecules in some cases
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