Commonly occurring product ions for PC(14:0/18:1(11Z))) (View full structure)
m/z
Ion Description
Structure (click to enlarge)
766.5159
Precursor ion [M.chloride]-
716.5236
Loss of CH3 and chloride from precursor ion
645.4501
Loss of choline and chloride from precursor ion
506.3252
Loss of sn1 acyl chain as ketene (RCH=C=O), CH3 and chloride from precursor ion
488.3147
Neutral loss of sn1 RCOOH group, loss of CH3 and chloride from precursor ion
452.2783
Loss of sn2 acyl chain as ketene (RCH=C=O), CH3 and chloride from precursor ion
434.2677
Neutral loss of sn2 RCOOH group, loss of CH3 and chloride from precursor ion
281.2486
sn2 RCOO- ion
227.2017
sn1 RCOO- ion
224.0693
Glycerophosphocholine with loss of CH3 and H2O
168.0431
Phosphocholine with loss of CH3
152.9958
Glycerol-3-phosphate ion with loss of H2O
96.9696
H2PO4- ion (from phosphate)
78.9591
PO3- ion (from phosphate)
Note: Structures of product ions may represent one of a number of possible isobaric molecules in some cases
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