Commonly occurring product ions for PC(15:1(9Z)/14:1(9Z))) (View full structure)

m/zIon DescriptionStructure (click to enlarge)
722.4533Precursor ion [M.chloride]-
672.4610Loss of CH3 and chloride from precursor ion
601.3875Loss of choline and chloride from precursor ion
464.2783Loss of sn2 acyl chain as ketene (RCH=C=O), CH3 and chloride from precursor ion
450.2626Loss of sn1 acyl chain as ketene (RCH=C=O), CH3 and chloride from precursor ion
446.2677Neutral loss of sn2 RCOOH group, loss of CH3 and chloride from precursor ion
432.2521Neutral loss of sn1 RCOOH group, loss of CH3 and chloride from precursor ion
239.2017sn1 RCOO- ion
225.1860sn2 RCOO- ion
224.0693Glycerophosphocholine with loss of CH3 and H2O
168.0431Phosphocholine with loss of CH3
152.9958Glycerol-3-phosphate ion with loss of H2O
96.9696H2PO4- ion (from phosphate)
78.9591PO3- ion (from phosphate)
Note: Structures of product ions may represent one of a number of possible isobaric molecules in some cases