Commonly occurring product ions for PC(18:1(11Z)/18:4(6Z,9Z,12Z,15Z))) (View full structure)
m/z
Ion Description
Structure (click to enlarge)
814.5159
Precursor ion [M.chloride]-
764.5236
Loss of CH3 and chloride from precursor ion
693.4501
Loss of choline and chloride from precursor ion
506.3252
Loss of sn2 acyl chain as ketene (RCH=C=O), CH3 and chloride from precursor ion
500.2783
Loss of sn1 acyl chain as ketene (RCH=C=O), CH3 and chloride from precursor ion
488.3147
Neutral loss of sn2 RCOOH group, loss of CH3 and chloride from precursor ion
482.2677
Neutral loss of sn1 RCOOH group, loss of CH3 and chloride from precursor ion
281.2486
sn1 RCOO- ion
275.2017
sn2 RCOO- ion
231.2118
Loss of CO2 from sn2 RCOO- ion (PUFA)
224.0693
Glycerophosphocholine with loss of CH3 and H2O
168.0431
Phosphocholine with loss of CH3
152.9958
Glycerol-3-phosphate ion with loss of H2O
96.9696
H2PO4- ion (from phosphate)
78.9591
PO3- ion (from phosphate)
Note: Structures of product ions may represent one of a number of possible isobaric molecules in some cases
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