Commonly occurring product ions for PC(18:4(6Z,9Z,12Z,15Z)/20:2(11Z,14Z))) (View full structure)
m/z
Ion Description
Structure (click to enlarge)
840.5316
Precursor ion [M.chloride]-
790.5392
Loss of CH3 and chloride from precursor ion
719.4657
Loss of choline and chloride from precursor ion
532.3409
Loss of sn1 acyl chain as ketene (RCH=C=O), CH3 and chloride from precursor ion
514.3303
Neutral loss of sn1 RCOOH group, loss of CH3 and chloride from precursor ion
500.2783
Loss of sn2 acyl chain as ketene (RCH=C=O), CH3 and chloride from precursor ion
482.2677
Neutral loss of sn2 RCOOH group, loss of CH3 and chloride from precursor ion
307.2643
sn2 RCOO- ion
275.2017
sn1 RCOO- ion
231.2118
Loss of CO2 from sn1 RCOO- ion (PUFA)
224.0693
Glycerophosphocholine with loss of CH3 and H2O
168.0431
Phosphocholine with loss of CH3
152.9958
Glycerol-3-phosphate ion with loss of H2O
96.9696
H2PO4- ion (from phosphate)
78.9591
PO3- ion (from phosphate)
Note: Structures of product ions may represent one of a number of possible isobaric molecules in some cases
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