Commonly occurring product ions for PE(P-18:0/18:4(6Z,9Z,12Z,15Z)) (View full structure)
| m/z | Ion Description | Structure (click to enlarge) |
|---|---|---|
| 722.5130 | Precursor ion [M-H]- |  |
| 472.2470 | Loss of plasmenyl group (RCH=CH2) from [M-H]- |  |
| 464.3147 | Loss of sn2 acyl chain as ketene (RCH=C=O) from [M-H]- |  |
| 454.2364 | Neutral loss of plasmenyl group RCH=CHOH) from [M-H]- |  |
| 446.3041 | Neutral loss of sn2 RCOOH group from [M-H]- |  |
| 275.2017 | sn2 RCOO- ion |  |
| 231.2118 | Loss of CO2 from sn2 RCOO- ion (PUFA) |  |
| 152.9958 | Glycerol-3-phosphate ion with loss of H2O |  |
| 140.0118 | Ethanolamine phosphate ion |  |
| 122.0013 | Ethanolamine phosphate ion with loss of H2O |  |
| 96.9696 | H2PO4- ion (from phosphate) |  |
| 78.9591 | PO3- ion (from phosphate) |  |