Commonly occurring product ions for PG(18:2(9Z,12Z)/16:1(9Z))) (View full structure)

m/zIon DescriptionStructure (click to enlarge)
743.4869Precursor ion [M-H]-
669.4501Loss of glycerol from precursor ion
507.2729Loss of sn2 acyl chain as ketene (RCH=C=O) from [M-H]-
489.2623Neutral loss of sn2 RCOOH group from [M-H]-
481.2572Loss of sn1 acyl chain as ketene (RCH=C=O) from [M-H]-
463.2466Neutral loss of sn1 RCOOH group from [M-H]-
433.2361Loss of sn2 acyl chain as ketene (RCH=C=O) and glycerol from [M-H]-
415.2255Neutral loss of sn2 RCOOH group and glycerol from [M-H]-
407.2204Loss of sn1 acyl chain as ketene (RCH=C=O) and glycerol from [M-H]-
389.2099Neutral loss of sn1 RCOOH group and glycerol from [M-H]-
279.2330sn1 RCOO- ion
253.2173sn2 RCOO- ion
245.0432Glycerophosphoglycerol ion
227.0326Glycerophosphoglycerol ion -H2O
209.0221Glycerophosphoglycerol ion -2H2O
152.9958Glycerol-3-phosphate ion with loss of H2O
96.9696H2PO4- ion (from phosphate)
78.9591PO3- ion (from phosphate)
Note: Structures of product ions may represent one of a number of possible isobaric molecules in some cases