Commonly occurring product ions for PG(18:4(6Z,9Z,12Z,15Z)/0:0)) (View full structure)
m/z
Ion Description
Structure (click to enlarge)
503.2416
Precursor ion [M-H]-
275.2017
sn1 RCOO- ion
245.0432
Glycerophosphoglycerol ion
245.0432
Loss of sn1 acyl chain as ketene (RCH=C=O) from [M-H]-
231.2118
Loss of CO2 from sn1 RCOO- ion (PUFA)
227.0326
Glycerophosphoglycerol ion -H2O
227.0326
Neutral loss of sn1 RCOOH group from [M-H]-
209.0221
Glycerophosphoglycerol ion -2H2O
171.0064
Loss of sn1 acyl chain as ketene (RCH=C=O) and glycerol from [M-H]-
152.9958
Glycerol-3-phosphate ion with loss of H2O
152.9958
Neutral loss of sn1 RCOOH group and glycerol from [M-H]-
96.9696
H2PO4- ion (from phosphate)
78.9591
PO3- ion (from phosphate)
Note: Structures of product ions may represent one of a number of possible isobaric molecules in some cases
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