Commonly occurring product ions for PG(19:0/14:0)) (View full structure)

m/zIon DescriptionStructure (click to enlarge)
735.5182Precursor ion [M-H]-
661.4814Loss of glycerol from precursor ion
525.3198Loss of sn2 acyl chain as ketene (RCH=C=O) from [M-H]-
507.3092Neutral loss of sn2 RCOOH group from [M-H]-
455.2416Loss of sn1 acyl chain as ketene (RCH=C=O) from [M-H]-
451.2830Loss of sn2 acyl chain as ketene (RCH=C=O) and glycerol from [M-H]-
437.2310Neutral loss of sn1 RCOOH group from [M-H]-
433.2725Neutral loss of sn2 RCOOH group and glycerol from [M-H]-
381.2048Loss of sn1 acyl chain as ketene (RCH=C=O) and glycerol from [M-H]-
363.1942Neutral loss of sn1 RCOOH group and glycerol from [M-H]-
297.2799sn1 RCOO- ion
245.0432Glycerophosphoglycerol ion
227.2017sn2 RCOO- ion
227.0326Glycerophosphoglycerol ion -H2O
209.0221Glycerophosphoglycerol ion -2H2O
152.9958Glycerol-3-phosphate ion with loss of H2O
96.9696H2PO4- ion (from phosphate)
78.9591PO3- ion (from phosphate)
Note: Structures of product ions may represent one of a number of possible isobaric molecules in some cases