Commonly occurring product ions for PG(22:1(11Z)/22:2(13Z,16Z))) (View full structure)

m/zIon DescriptionStructure (click to enlarge)
883.6434Precursor ion [M-H]-
809.6066Loss of glycerol from precursor ion
565.3511Loss of sn2 acyl chain as ketene (RCH=C=O) from [M-H]-
563.3355Loss of sn1 acyl chain as ketene (RCH=C=O) from [M-H]-
547.3405Neutral loss of sn2 RCOOH group from [M-H]-
545.3249Neutral loss of sn1 RCOOH group from [M-H]-
491.3143Loss of sn2 acyl chain as ketene (RCH=C=O) and glycerol from [M-H]-
489.2987Loss of sn1 acyl chain as ketene (RCH=C=O) and glycerol from [M-H]-
473.3038Neutral loss of sn2 RCOOH group and glycerol from [M-H]-
471.2881Neutral loss of sn1 RCOOH group and glycerol from [M-H]-
337.3112sn1 RCOO- ion
335.2956sn2 RCOO- ion
245.0432Glycerophosphoglycerol ion
227.0326Glycerophosphoglycerol ion -H2O
209.0221Glycerophosphoglycerol ion -2H2O
152.9958Glycerol-3-phosphate ion with loss of H2O
96.9696H2PO4- ion (from phosphate)
78.9591PO3- ion (from phosphate)
Note: Structures of product ions may represent one of a number of possible isobaric molecules in some cases