Commonly occurring product ions for PG(22:2(13Z,16Z)/22:4(7Z,10Z,13Z,16Z))) (View full structure)
| m/z | Ion Description | Structure (click to enlarge) |
|---|---|---|
| 877.5964 | Precursor ion [M-H]- |  |
| 803.5596 | Loss of glycerol from precursor ion |  |
| 563.3355 | Loss of sn2 acyl chain as ketene (RCH=C=O) from [M-H]- |  |
| 559.3042 | Loss of sn1 acyl chain as ketene (RCH=C=O) from [M-H]- |  |
| 545.3249 | Neutral loss of sn2 RCOOH group from [M-H]- |  |
| 541.2936 | Neutral loss of sn1 RCOOH group from [M-H]- |  |
| 489.2987 | Loss of sn2 acyl chain as ketene (RCH=C=O) and glycerol from [M-H]- |  |
| 485.2674 | Loss of sn1 acyl chain as ketene (RCH=C=O) and glycerol from [M-H]- |  |
| 471.2881 | Neutral loss of sn2 RCOOH group and glycerol from [M-H]- |  |
| 467.2568 | Neutral loss of sn1 RCOOH group and glycerol from [M-H]- |  |
| 335.2956 | sn1 RCOO- ion |  |
| 331.2643 | sn2 RCOO- ion |  |
| 287.2744 | Loss of CO2 from sn2 RCOO- ion (PUFA) |  |
| 245.0432 | Glycerophosphoglycerol ion |  |
| 227.0326 | Glycerophosphoglycerol ion -H2O |  |
| 209.0221 | Glycerophosphoglycerol ion -2H2O |  |
| 152.9958 | Glycerol-3-phosphate ion with loss of H2O |  |
| 96.9696 | H2PO4- ion (from phosphate) |  |
| 78.9591 | PO3- ion (from phosphate) |  |