Commonly occurring product ions for PI(10:0/16:0)) (View full structure)

m/zIon DescriptionStructure (click to enlarge)
725.4247Precursor ion [M-H]-
571.2889Loss of sn1 acyl chain as ketene (RCH=C=O) from [M-H]-
563.3718Loss of inositol from [M-H]-
553.2783Neutral loss of sn1 RCOOH group from [M-H]-
487.1950Loss of sn2 acyl chain as ketene (RCH=C=O) from [M-H]-
469.1844Neutral loss of sn2 RCOOH group from [M-H]-
409.2361Loss of sn1 acyl chain as ketene (RCH=C=O) and inositol from [M-H]-
391.2255Neutral loss of sn1 RCOOH group and inositol from [M-H]-
325.1422Loss of sn2 acyl chain as ketene (RCH=C=O) and inositol from [M-H]-
315.0487Glycerophosphoinositol -H2O
307.1316Neutral loss of sn2 RCOOH group and inositol from [M-H]-
297.0381Glycerophosphoinositol -2H2O
259.0225Inositol phosphate ion
255.2330sn2 RCOO- ion
241.0119Inositol phosphate ion - H2O
223.0013Inositol phosphate ion - 2 H2O
171.1391sn1 RCOO- ion
152.9958Glycerol-3-phosphate ion with loss of H2O
96.9696H2PO4- ion (from phosphate)
78.9591PO3- ion (from phosphate)
Note: Structures of product ions may represent one of a number of possible isobaric molecules in some cases