Commonly occurring product ions for PI(14:0/22:0)) (View full structure)
| m/z | Ion Description | Structure (click to enlarge) |
|---|---|---|
| 865.5812 | Precursor ion [M-H]- |  |
| 703.5283 | Loss of inositol from [M-H]- |  |
| 655.3828 | Loss of sn1 acyl chain as ketene (RCH=C=O) from [M-H]- |  |
| 637.3722 | Neutral loss of sn1 RCOOH group from [M-H]- |  |
| 543.2576 | Loss of sn2 acyl chain as ketene (RCH=C=O) from [M-H]- |  |
| 525.2470 | Neutral loss of sn2 RCOOH group from [M-H]- |  |
| 493.3300 | Loss of sn1 acyl chain as ketene (RCH=C=O) and inositol from [M-H]- |  |
| 475.3194 | Neutral loss of sn1 RCOOH group and inositol from [M-H]- |  |
| 381.2048 | Loss of sn2 acyl chain as ketene (RCH=C=O) and inositol from [M-H]- |  |
| 363.1942 | Neutral loss of sn2 RCOOH group and inositol from [M-H]- |  |
| 339.3269 | sn2 RCOO- ion |  |
| 315.0487 | Glycerophosphoinositol -H2O |  |
| 297.0381 | Glycerophosphoinositol -2H2O |  |
| 259.0225 | Inositol phosphate ion |  |
| 241.0119 | Inositol phosphate ion - H2O |  |
| 227.2017 | sn1 RCOO- ion |  |
| 223.0013 | Inositol phosphate ion - 2 H2O |  |
| 152.9958 | Glycerol-3-phosphate ion with loss of H2O |  |
| 96.9696 | H2PO4- ion (from phosphate) |  |
| 78.9591 | PO3- ion (from phosphate) |  |