Commonly occurring product ions for PI(18:1(9Z)/19:1(9Z))) (View full structure)
| m/z | Ion Description | Structure (click to enlarge) |
|---|---|---|
| 875.5655 | Precursor ion [M-H]- |  |
| 713.5127 | Loss of inositol from [M-H]- |  |
| 611.3202 | Loss of sn1 acyl chain as ketene (RCH=C=O) from [M-H]- |  |
| 597.3045 | Loss of sn2 acyl chain as ketene (RCH=C=O) from [M-H]- |  |
| 593.3096 | Neutral loss of sn1 RCOOH group from [M-H]- |  |
| 579.2940 | Neutral loss of sn2 RCOOH group from [M-H]- |  |
| 449.2674 | Loss of sn1 acyl chain as ketene (RCH=C=O) and inositol from [M-H]- |  |
| 435.2517 | Loss of sn2 acyl chain as ketene (RCH=C=O) and inositol from [M-H]- |  |
| 431.2568 | Neutral loss of sn1 RCOOH group and inositol from [M-H]- |  |
| 417.2412 | Neutral loss of sn2 RCOOH group and inositol from [M-H]- |  |
| 315.0487 | Glycerophosphoinositol -H2O |  |
| 297.0381 | Glycerophosphoinositol -2H2O |  |
| 295.2643 | sn2 RCOO- ion |  |
| 281.2486 | sn1 RCOO- ion |  |
| 259.0225 | Inositol phosphate ion |  |
| 241.0119 | Inositol phosphate ion - H2O |  |
| 223.0013 | Inositol phosphate ion - 2 H2O |  |
| 152.9958 | Glycerol-3-phosphate ion with loss of H2O |  |
| 96.9696 | H2PO4- ion (from phosphate) |  |
| 78.9591 | PO3- ion (from phosphate) |  |