Commonly occurring product ions for PI(18:4(6Z,9Z,12Z,15Z)/0:0)) (View full structure)
| m/z | Ion Description | Structure (click to enlarge) |
|---|---|---|
| 591.2576 | Precursor ion [M-H]- |  |
| 429.2048 | Loss of inositol from [M-H]- |  |
| 333.0592 | Loss of sn1 acyl chain as ketene (RCH=C=O) from [M-H]- |  |
| 315.0487 | Glycerophosphoinositol -H2O |  |
| 315.0487 | Neutral loss of sn1 RCOOH group from [M-H]- | |
| 297.0381 | Glycerophosphoinositol -2H2O |  |
| 275.2017 | sn1 RCOO- ion |  |
| 259.0225 | Inositol phosphate ion |  |
| 241.0119 | Inositol phosphate ion - H2O |  |
| 231.2118 | Loss of CO2 from sn1 RCOO- ion (PUFA) |  |
| 223.0013 | Inositol phosphate ion - 2 H2O |  |
| 171.0064 | Loss of sn1 acyl chain as ketene (RCH=C=O) and inositol from [M-H]- |  |
| 152.9958 | Glycerol-3-phosphate ion with loss of H2O |  |
| 152.9958 | Neutral loss of sn1 RCOOH group and inositol from [M-H]- | |
| 96.9696 | H2PO4- ion (from phosphate) |  |
| 78.9591 | PO3- ion (from phosphate) |  |