Commonly occurring product ions for PS(15:0/2:0) (View full structure)

m/zIon DescriptionStructure (click to enlarge)
524.2630Precursor ion [M-H]-
437.2310Loss of serine from precursor ion
395.2204Loss of sn2 acyl chain as ketene (RCH=C=O) and serine from [M-H]-
377.2099Neutral loss of sn2 RCOOH group and serine from [M-H]-
241.2173sn1 RCOO- ion
213.0170Loss of sn1 acyl chain as ketene (RCH=C=O) and serine from [M-H]-
195.0064Neutral loss of sn1 RCOOH group and serine from [M-H]-
152.9958Glycerol-3-phosphate ion with loss of H2O
96.9696H2PO4- ion (from phosphate)
78.9591PO3- ion (from phosphate)
59.0139sn2 RCOO- ion
Note: Structures of product ions may represent one of a number of possible isobaric molecules in some cases