Commonly occurring product ions for PS(18:4(9E,11E,13E,15E)/15:0) (View full structure)

m/zIon DescriptionStructure (click to enlarge)
740.4508Precursor ion [M-H]-
653.4188Loss of serine from precursor ion
429.2048Loss of sn2 acyl chain as ketene (RCH=C=O) and serine from [M-H]-
411.1942Neutral loss of sn2 RCOOH group and serine from [M-H]-
395.2204Loss of sn1 acyl chain as ketene (RCH=C=O) and serine from [M-H]-
377.2099Neutral loss of sn1 RCOOH group and serine from [M-H]-
275.2017sn1 RCOO- ion
241.2173sn2 RCOO- ion
231.2118Loss of CO2 from sn1 RCOO- ion (PUFA)
152.9958Glycerol-3-phosphate ion with loss of H2O
96.9696H2PO4- ion (from phosphate)
78.9591PO3- ion (from phosphate)
Note: Structures of product ions may represent one of a number of possible isobaric molecules in some cases