Commonly occurring product ions for PS(27:0/4:0) (View full structure)

m/zIon DescriptionStructure (click to enlarge)
720.4821Precursor ion [M-H]-
633.4501Loss of serine from precursor ion
563.4082Loss of sn2 acyl chain as ketene (RCH=C=O) and serine from [M-H]-
545.3977Neutral loss of sn2 RCOOH group and serine from [M-H]-
409.4051sn1 RCOO- ion
241.0483Loss of sn1 acyl chain as ketene (RCH=C=O) and serine from [M-H]-
223.0377Neutral loss of sn1 RCOOH group and serine from [M-H]-
152.9958Glycerol-3-phosphate ion with loss of H2O
96.9696H2PO4- ion (from phosphate)
87.0452sn2 RCOO- ion
78.9591PO3- ion (from phosphate)
Note: Structures of product ions may represent one of a number of possible isobaric molecules in some cases