Commonly occurring product ions for PS(28:0/19:0) (View full structure)

m/zIon DescriptionStructure (click to enlarge)
944.7325Precursor ion [M-H]-
857.7005Loss of serine from precursor ion
577.4239Loss of sn2 acyl chain as ketene (RCH=C=O) and serine from [M-H]-
559.4133Neutral loss of sn2 RCOOH group and serine from [M-H]-
451.2830Loss of sn1 acyl chain as ketene (RCH=C=O) and serine from [M-H]-
433.2725Neutral loss of sn1 RCOOH group and serine from [M-H]-
423.4208sn1 RCOO- ion
297.2799sn2 RCOO- ion
152.9958Glycerol-3-phosphate ion with loss of H2O
96.9696H2PO4- ion (from phosphate)
78.9591PO3- ion (from phosphate)
Note: Structures of product ions may represent one of a number of possible isobaric molecules in some cases