Commonly occurring product ions for PS(P-18:0/22:4(7Z,10Z,13Z,16Z))) (View full structure)

m/zIon DescriptionStructure (click to enlarge)
822.5655Precursor ion [M-H]-
735.5334Loss of serine from precursor ion
421.2725Loss of sn2 acyl chain as ketene (RCH=C=O) and serine from [M-H]-
403.2619Neutral loss of sn2 RCOOH group and serine from [M-H]-
331.2643sn2 RCOO- ion
287.2744Loss of CO2 from sn2 RCOO- ion (PUFA)
152.9958Glycerol-3-phosphate ion with loss of H2O
96.9696H2PO4- ion (from phosphate)
78.9591PO3- ion (from phosphate)
Note: Structures of product ions may represent one of a number of possible isobaric molecules in some cases