Structure Database (LMSD)

Common Name
15-OxoEDE
Systematic Name
15-oxo-11Z,13E-eicosadienoic acid
Synonyms
LM ID
LMFA01060073
Formula
Exact Mass
Calculate m/z
322.250795
Sum Composition
Status
Curated



Classification

Biological Context

15-OxoEDE is produced by the oxidation of 15-HEDE. 15-OxoEDE inhibits 5-LO from RBL-1 cells with an IC50 of 55 µM, which is about 2-fold lower than 15(S)-HEDE.1 A related oxo-eicosanoid, 5-oxoETE, is biosynthesized from 5(S)-HETE by a specific dehydrogenase and has potent inflammatory activity.2

This information has been provided by Cayman Chemical

References

1. Powell, W.S., Gravelle, F., and Gravel, S. Metabolism of 5(S)-hydroxy-6,8,11,14-eicosatetraenoic acid and other 5(S)-hydroxyeicosanoids by a specific dehydrogenase in human polymorphonuclear leukocytes. J. Biol. Chem. 267(27), 19233-19241 (1992).

References

Taxonomy Information

Curated from
NCBI taxonomy class
Reference
synthetic construct (#32630)
Structural requirements for the inhibition of 5-lipoxygenase by 15-hydroxyeicosa-5,8,11,13-tetraenoic acid analogues.,
J Med Chem, 1987
Pubmed ID: 3806609

String Representations

InChiKey (Click to copy)
QZCMHXPXGACWLJ-QWAPPMFBSA-N
InChi (Click to copy)
InChI=1S/C20H34O3/c1-2-3-13-16-19(21)17-14-11-9-7-5-4-6-8-10-12-15-18-20(22)23/h9,11,14,17H,2-8,10,12-13,15-16,18H2,1H3,(H,22,23)/b11-9-,17-14+
SMILES (Click to copy)
C(/C=C\C=C\C(=O)CCCCC)CCCCCCCCC(=O)O

Other Databases

CHEBI ID
LIPIDBANK ID
DFA8155
PubChem CID
Cayman ID

Calculated Physicochemical Properties

Heavy Atoms 23
Rings 0
Aromatic Rings 0
Rotatable Bonds 16
Van der Waals Molecular Volume 370.37
Topological Polar Surface Area 54.37
Hydrogen Bond Donors 1
Hydrogen Bond Acceptors 3
logP 5.84
Molar Refractivity 96.62

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Created at
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Updated at
14th Nov 2024