Structure Database (LMSD)

Common Name
clavulone II
Systematic Name
methyl 4R,12S-diacetoxy-9-oxo-5E,7E,10Z,13Z-prostatetraenoate-cyclo[8,12]
Synonyms
LM ID
LMFA03120002
Formula
C25H34O7
Exact Mass
Calculate m/z
446.230455
Sum Composition
FA 25:8;O5
Status
Active
Show lipids differing only in stereochemistry/bond geometry

Classification

Category
Main Class
Sub Class
Fatty Acyls [FA]
Eicosanoids [FA03]
Clavulones [FA0312]
Fatty Acids and Conjugates [FA01]
Unsaturated fatty acids [FA0103]
Oxo fatty acids [FA0106]
Carbocyclic fatty acids [FA0114]

References

Taxonomy Information

Curated from
NCBI taxonomy class
Reference
Clavularia viridis (#153213)
Anthozoa (#6101)
Absolute stereochemistry of new prostanoids clavulone I, II and III, from Clavularia viridis Quoy and Gaimard,
Tetrahedron Letts, 1983

String Representations

InChiKey (Click to copy)
QXSYLWTUKSQQCP-VZCZYXORSA-N
InChi (Click to copy)
InChI=1S/C25H34O7/c1-5-6-7-8-9-10-17-25(32-20(3)27)18-16-23(28)22(25)13-11-12-21(31-19(2)26)14-15-24(29)30-4/h9-13,16,18,21H,5-8,14-15,17H2,1-4H3/b10-9-,12-11+,22-13-/t21-,25-/m0/s1
SMILES (Click to copy)
[C@]1(OC(C)=O)(C/C=C\CCCCC)C=CC(=O)/C/1=C/C=C/[C@H](OC(=O)C)CCC(=O)OC

Other Databases

KEGG ID
C13812
CHEBI ID
34643
LIPIDBANK ID
XPR8002
PubChem CID
5283218

Calculated Physicochemical Properties

Heavy Atoms 32
Rings 1
Aromatic Rings 0
Rotatable Bonds 16
Van der Waals Molecular Volume 469.11
Topological Polar Surface Area 95.97
Hydrogen Bond Donors 0
Hydrogen Bond Acceptors 7
logP 4.89
Molar Refractivity 121.59

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Created at
-
Updated at
5th Apr 2022