Structure Database (LMSD)

Common Name
Arabidopside E
Systematic Name
1-((1S,2S)-3-oxo-2-(2'Z-pentenyl)cyclopent-4-eneoctanoyl)-2-(1S,2S)-3-oxo-2- (2'Z-pentenyl)cyclopent-4-enehexanoyl)-3-O-(6'-O-((1S,2S)-3-oxo-2-(2'Z-pentenyl)cyclopent-4-eneoctanoyl)-β-D-galactosyl-sn-glycerol
Synonyms
  • 1-O-(12-oxo-phytodienoyl)-2-O-(2,3-dinor-12-oxo-phytodienoyl)-3-O-(6'-O-(12-oxo-phytodienoyl)-beta-D-galactopyranosyl)-sn-glycerol
LM ID
LMGL05010038
Formula
Exact Mass
Calculate m/z
1048.64871
Status
Active

Classification

References

Taxonomy Information

Curated from
NCBI taxonomy class
Reference
Arabidopsis thaliana (#3702)
Magnoliopsida (#3398)
Oxylipin profiling of the hypersensitive response in Arabidopsis thaliana. Formation of a novel oxo-phytodienoic acid-containing galactolipid, arabidopside E.,
J Biol Chem, 2006
Pubmed ID: 16923817

String Representations

InChiKey (Click to copy)
XIDQMQJGTGDFQK-VCLRQILYSA-N
InChi (Click to copy)
InChI=1S/C61H92O14/c1-4-7-17-29-48-44(35-38-51(48)62)26-20-12-10-14-23-32-55(65)71-41-47(74-57(67)34-25-16-22-28-46-37-40-53(64)50(46)31-19-9-6-3)42-73-61-60(70)59(69)58(68)54(75-61)43-72-56(66)33-24-15-11-13-21-27-45-36-39-52(63)49(45)30-18-8-5-2/h7-9,17-19,35-40,44-50,54,58-61,68-70H,4-6,10-16,20-34,41-43H2,1-3H3/b17-7-,18-8-,19-9-/t44-,45-,46-,47+,48-,49-,50-,54+,58-,59-,60+,61+/m0/s1
SMILES (Click to copy)
C(O[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](COC(CCCCCCC[C@H]2C=CC(=O)[C@H]2C/C=C\CC)=O)O1)[C@]([H])(OC(CCCCC[C@H]1C=CC(=O)[C@H]1C/C=C\CC)=O)COC(CCCCCCC[C@H]1C=CC(=O)[C@H]1C/C=C\CC)=O

Other Databases

PubChem CID

Calculated Physicochemical Properties

Heavy Atoms 75
Rings 4
Aromatic Rings 0
Rotatable Bonds 42
Van der Waals Molecular Volume 1105.80
Topological Polar Surface Area 211.33
Hydrogen Bond Donors 3
Hydrogen Bond Acceptors 14
logP 12.98
Molar Refractivity 292.22

Admin

Created at
2nd Aug 2020
Updated at
22nd Mar 2024
LIPID MAPS® abbreviations for glycerolipids (GL)

The LIPID MAPS® glycerolipid abbreviations (MG,DG,TG) are used here to refer to species with one, two or three radyl side-chains, respectively, where the structures of the side chains are indicated within parentheses in the 'Prefix(sn1/sn2/sn3)' format (e.g. TG(16:0/18:1(9Z)/18:0). Acyl chains are assumed by default. The alkyl ether linkage is represented by the 'O-' prefix, e.g. DG(O-16:0/18:1(9Z)/0:0), whereas the 1Z-alkenyl ether (Plasmalogen) linkage is represented by the 'P-' prefix, e.g. and DG(P-14:0/18:1(9Z)/0:0).

For Diradylglycerols and Triradylglycerols, it is not always possible to experimentally determine the exact position of radyl groups on the glycerol group. For Diradylglycerols with two different radyl groups, two different structural isomers exist. For Triradylglycerols with three different radyl groups, six different isomers exist.

Instead of drawing all possible structural isomers explicitly for Diradylglycerols and Triradylglycerols, the LIPID MAPS® abbreviation scheme supports the isomeric specification. A suffix containing 'iso' along with the number of possible isomers is appended to the abbreviation (e.g. [iso2],[iso6]) and a single unique LM_ID is assigned. The structure assigned to the LM_ID corresponds to the radyl substitution shown in the abbreviation. An option is provided to display the other isomers in the group.

The [rac] designation refers to racemic mixtures due to substitution at the sn1 and sn3 positions of glycerol.