Structure Database (LMSD)
Common Name
Arabidopside E
Systematic Name
1-((1S,2S)-3-oxo-2-(2'Z-pentenyl)cyclopent-4-eneoctanoyl)-2-(1S,2S)-3-oxo-2- (2'Z-pentenyl)cyclopent-4-enehexanoyl)-3-O-(6'-O-((1S,2S)-3-oxo-2-(2'Z-pentenyl)cyclopent-4-eneoctanoyl)-β-D-galactosyl-sn-glycerol
Synonyms
- 1-O-(12-oxo-phytodienoyl)-2-O-(2,3-dinor-12-oxo-phytodienoyl)-3-O-(6?-O-(12-oxo-phytodienoyl)-beta-D-galactopyranosyl)-sn-glycerol
Main
Classification
Category
Main Class
Sub Class
String Representations
InChiKey (Click to copy)
XIDQMQJGTGDFQK-VCLRQILYSA-N
InChi (Click to copy)
InChI=1S/C61H92O14/c1-4-7-17-29-48-44(35-38-51(48)62)26-20-12-10-14-23-32-55(65)71-41-47(74-57(67)34-25-16-22-28-46-37-40-53(64)50(46)31-19-9-6-3)42-73-61-60(70)59(69)58(68)54(75-61)43-72-56(66)33-24-15-11-13-21-27-45-36-39-52(63)49(45)30-18-8-5-2/h7-9,17-19,35-40,44-50,54,58-61,68-70H,4-6,10-16,20-34,41-43H2,1-3H3/b17-7-,18-8-,19-9-/t44-,45-,46-,47+,48-,49-,50-,54+,58-,59-,60+,61+/m0/s1
SMILES (Click to copy)
C(O[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](COC(CCCCCCC[C@H]2C=CC(=O)[C@H]2C/C=C\CC)=O)O1)[C@]([H])(OC(CCCCC[C@H]1C=CC(=O)[C@H]1C/C=C\CC)=O)COC(CCCCCCC[C@H]1C=CC(=O)[C@H]1C/C=C\CC)=O
References
Taxonomy Information
Curated from
NCBI taxonomy class
Reference
Arabidopsis thaliana
(#3702)
Magnoliopsida
(#3398)
Oxylipin profiling of the hypersensitive response in Arabidopsis thaliana. Formation of a novel oxo-phytodienoic acid-containing galactolipid, arabidopside E.,
J Biol Chem, 2006
J Biol Chem, 2006
Pubmed ID:
16923817
Other Databases
PubChem CID
Calculated Physicochemical Properties
Heavy Atoms
75
Rings
4
Aromatic Rings
0
Rotatable Bonds
42
Van der Waals Molecular Volume
1105.80
Topological Polar Surface Area
211.33
Hydrogen Bond Donors
3
Hydrogen Bond Acceptors
14
logP
12.98
Molar Refractivity
292.22
Admin
Created at
2nd Aug 2020
Updated at
28th Jan 2021
LIPID MAPS® abbreviations for glycerolipids (GL)
The LIPID MAPS® glycerolipid abbreviations (MG,DG,TG) are used here to refer to species with one, two or three radyl side-chains, respectively, where the structures of the side chains are indicated within parentheses in the 'Prefix(sn1/sn2/sn3)' format (e.g. TG(16:0/18:1(9Z)/18:0). Acyl chains are assumed by default. The alkyl ether linkage is represented by the 'O-' prefix, e.g. DG(O-16:0/18:1(9Z)/0:0), whereas the 1Z-alkenyl ether (Plasmalogen) linkage is represented by the 'P-' prefix, e.g. and DG(P-14:0/18:1(9Z)/0:0).
For Diradylglycerols and Triradylglycerols, it is not always possible to experimentally determine the exact position of radyl groups on the glycerol group. For Diradylglycerols with two different radyl groups, two different structural isomers exist. For Triradylglycerols with three different radyl groups, six different isomers exist.
Instead of drawing all possible structural isomers explicitly for Diradylglycerols and Triradylglycerols, the LIPID MAPS® abbreviation scheme supports the isomeric specification. A suffix containing 'iso' along with the number of possible isomers is appended to the abbreviation (e.g. [iso2],[iso6]) and a single unique LM_ID is assigned. The structure assigned to the LM_ID corresponds to the radyl substitution shown in the abbreviation. An option is provided to display the other isomers in the group.
The [rac] designation refers to racemic mixtures due to substitution at the sn1 and sn3 positions of glycerol.
The LIPID MAPS® glycerolipid abbreviations (MG,DG,TG) are used here to refer to species with one, two or three radyl side-chains, respectively, where the structures of the side chains are indicated within parentheses in the 'Prefix(sn1/sn2/sn3)' format (e.g. TG(16:0/18:1(9Z)/18:0). Acyl chains are assumed by default. The alkyl ether linkage is represented by the 'O-' prefix, e.g. DG(O-16:0/18:1(9Z)/0:0), whereas the 1Z-alkenyl ether (Plasmalogen) linkage is represented by the 'P-' prefix, e.g. and DG(P-14:0/18:1(9Z)/0:0).
For Diradylglycerols and Triradylglycerols, it is not always possible to experimentally determine the exact position of radyl groups on the glycerol group. For Diradylglycerols with two different radyl groups, two different structural isomers exist. For Triradylglycerols with three different radyl groups, six different isomers exist.
Instead of drawing all possible structural isomers explicitly for Diradylglycerols and Triradylglycerols, the LIPID MAPS® abbreviation scheme supports the isomeric specification. A suffix containing 'iso' along with the number of possible isomers is appended to the abbreviation (e.g. [iso2],[iso6]) and a single unique LM_ID is assigned. The structure assigned to the LM_ID corresponds to the radyl substitution shown in the abbreviation. An option is provided to display the other isomers in the group.
The [rac] designation refers to racemic mixtures due to substitution at the sn1 and sn3 positions of glycerol.