LIPID MAPS

Structure Database (LMSD)

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Common Name

PAT18(25:1(2E)(2Me,4Me[S],6Me[S])/25:1(2E)(2Me,4Me[S],6Me[S])/26:1(2E)(2Me,4Me[S],6Me[S])/24:0(2Me[R],3OH[R],4Me[S],6Me[S]))

Systematic Name

2-octadecanoyl-3-O-(2,4S,6S-trimethyl-2E-pentacosenoyl)-6-O-(2,4S,6S-trimethyl-2E-pentacosenoyl)-2'-O-(2,4S,6S-trimethyl-2E-hexacosenoyl)-4'-O-(2R,4S,6S-trimethyl-3R-hydroxy-tetracosanoyl)-α,α-trehalose

Synonyms

LM ID

LMSL03000966

Formula

C₁₄₂H₂₆₆O₁₇

Exact Mass

Calculate m/z

2243.995005

Status

Active (generated by computational methods)

Show lipids differing only in stereochemistry/bond geometry

Classification

References

Taxonomy Information

Curated from

NCBI taxonomy class

Reference

Mycobacterium (#1763)

Actinomycetes (#1760)

Mycobacterial polyacyltrehalose generated by computational means

Mycobacterium tuberculosis (#1773)

Actinomycetes (#1760)

Asymmetric Total Synthesis and Structural Revision of DAT₂, an Antigenic Glycolipid from Mycobacterium tuberculosis.,
Angew Chem Int Ed Engl, 2024

Pubmed ID: 38456226

String Representations

InChiKey (Click to copy)

YKOWHKGHSXISNN-YSWPYMMDSA-N

InChi (Click to copy)

InChI=1S/C142H266O17/c1-18-23-28-33-38-43-48-53-58-62-65-70-73-78-83-88-93-98-103-117(8)108-121(12)112-125(16)139(150)158-135-132(147)133(156-140(151)126(17)130(145)122(13)109-118(9)104-99-94-89-84-79-74-67-61-56-51-46-41-36-31-26-21-4)127(113-143)153-141(135)159-142-136(155-129(144)105-100-95-90-85-80-75-66-57-52-47-42-37-32-27-22-5)134(157-138(149)124(15)111-120(11)107-116(7)102-97-92-87-82-77-72-69-64-60-55-50-45-40-35-30-25-20-3)131(146)128(154-142)114-152-137(148)123(14)110-119(10)106-115(6)101-96-91-86-81-76-71-68-63-59-54-49-44-39-34-29-24-19-2/h110-112,115-122,126-128,130-136,141-143,145-147H,18-109,113-114H2,1-17H3/b123-110+,124-111+,125-112+/t115-,116-,117-,118-,119-,120-,121-,122-,126+,127+,128+,130+,131+,132-,133+,134-,135+,136+,141+,142+/m0/s1

SMILES (Click to copy)

CCCCCCCCCCCCCCCCCCCC[C@H](C)C[C@H](C)/C=C(\C)/C(=O)O[C@@H]1[C@H]([C@@H]([C@@H](CO)O[C@@H]1O[C@@H]1[C@@H]([C@H]([C@@H]([C@@H](COC(=O)/C(=C/[C@@H](C)C[C@@H](C)CCCCCCCCCCCCCCCCCCC)/C)O1)O)OC(=O)/C(=C/[C@@H](C)C[C@@H](C)CCCCCCCCCCCCCCCCCCC)/C)OC(=O)CCCCCCCCCCCCCCCCC)OC(=O)[C@H](C)[C@@H]([C@@H](C)C[C@@H](C)CCCCCCCCCCCCCCCCCC)O)O