Structure Database (LMSD)

OH H NH OH O OH H
Common Name
Cer(d18:1(4E)/27:0(3OH))
Systematic Name
N-(3R-hydroxy-heptacosanoyl)-sphing-4-enine
Synonyms
  • N-(3R-hydroxy-heptacosanoyl)-sphingosine
  • Cer[BS]
LM ID
LMSP02010206
Formula
C45H89NO4
Exact Mass
Calculate m/z
707.679159
Sum Composition
Cer 45:1;O3
Abbrev Chains
Cer 18:1;O2/27:0;O
Status
Active
Show lipids differing only in stereochemistry/bond geometry

Main

Classification

Category
Main Class
Sub Class
Sphingolipids [SP]
Ceramides [SP02]
N-acylsphingosines (ceramides) [SP0201]

String Representations

InChiKey (Click to copy)
UDMXFTMJCAYYSY-OSTLLPERSA-N
InChi (Click to copy)
InChI=1S/C45H89NO4/c1-3-5-7-9-11-13-15-17-18-19-20-21-22-23-24-25-27-28-30-32-34-36-38-42(48)40-45(50)46-43(41-47)44(49)39-37-35-33-31-29-26-16-14-12-10-8-6-4-2/h37,39,42-44,47-49H,3-36,38,40-41H2,1-2H3,(H,46,50)/b39-37+/t42-,43+,44-/m1/s1
SMILES (Click to copy)
[C@](CO)([H])(NC(C[C@H](O)CCCCCCCCCCCCCCCCCCCCCCCC)=O)[C@]([H])(O)/C=C/CCCCCCCCCCCCC

References

Taxonomy Information

Curated from
NCBI taxonomy class
Reference
Homo sapiens (#9606)
Mammalia (#40674)
Comparative profiling and comprehensive quantification of stratum corneum ceramides in humans and mice by LC/MS/MS.,
J Lipid Res, 2020
Pubmed ID: 32265320

Other Databases

PubChem CID
171119486

Calculated Physicochemical Properties

Heavy Atoms 50
Rings 0
Aromatic Rings 0
Rotatable Bonds 41
Van der Waals Molecular Volume 827.94
Topological Polar Surface Area 89.79
Hydrogen Bond Donors 4
Hydrogen Bond Acceptors 5
logP 13.97
Molar Refractivity 219.76

Reactions

Filter by species:
ⓘ Reactions are shown if the E.C. number of the enzyme catalysing it is annotated in the UniProt database for a species belonging to the selected taxonomic class.
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Reactions graph legend

Admin

Created at
8th Jun 2020
Updated at
8th Jun 2020