Structure Database (LMSD)

Common Name
15R-PGE2
Systematic Name
9-oxo-11R,15R-dihydroxy-5Z,13E-prostadienoic acid
Synonyms
  • 15R-Prostaglandin E2
  • 8,15-diepi-15-E2t-IsoP
  • 9-oxo-11R,15R-dihydroxy-5Z,13E-prostadienoic acid-cyclo[8R,12R]
LM ID
LMFA03010094
Formula
Exact Mass
Calculate m/z
352.224975
Sum Composition
Status
Curated

Classification

Biological Context

15(R)-Prostaglandin E2 (15(R)-PGE2) is the C-15 epimer of the naturally occurring 15(S)-PGE2. 15(R)-PGE2 is much less potent than the natural stereoisomer in most biological assays. In hamsters, a dose of 0.20 mg of PGE2 inhibits fertility by 100%, whereas a dose of 1.0 mg of 15(R)-PGE2 inhibits fertility by only 17%.1 15(R)-PGE2 occurs as a minor impurity in some pharmaceutical formulations of PGE2 used in obstetrics.

This information has been provided by Cayman Chemical

References

1. Miller, W.L., and Sutton, M.J. Relative biological activity of certain prostaglandins and their enantiomers. Prostaglandins 11(1), 77-84 (1976).

References

Taxonomy Information

Curated from
NCBI taxonomy class
Reference
Plexaura homomalla (#47982)
Anthozoa (#6101)
Identification of prostaglandins in the gorgonian, Plexaura homomalla.,
Eur J Biochem, 1972
Pubmed ID: 4403575

String Representations

InChiKey (Click to copy)
XEYBRNLFEZDVAW-GKEZHNTDSA-N
InChi (Click to copy)
InChI=1S/C20H32O5/c1-2-3-6-9-15(21)12-13-17-16(18(22)14-19(17)23)10-7-4-5-8-11-20(24)25/h4,7,12-13,15-17,19,21,23H,2-3,5-6,8-11,14H2,1H3,(H,24,25)/b7-4-,13-12+/t15-,16-,17-,19-/m1/s1
SMILES (Click to copy)
[C@H]1(/C=C/[C@H](O)CCCCC)[C@H](O)CC(=O)[C@@H]1C/C=C\CCCC(=O)O

Other Databases

LIPIDBANK ID
XPR8048
PubChem CID
Cayman ID

Calculated Physicochemical Properties

Heavy Atoms 25
Rings 1
Aromatic Rings 0
Rotatable Bonds 12
Van der Waals Molecular Volume 375.59
Topological Polar Surface Area 94.83
Hydrogen Bond Donors 3
Hydrogen Bond Acceptors 5
logP 3.82
Molar Refractivity 98.17

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Updated at
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