Commonly occurring product ions for PC(O-14:0/24:4(5Z,8Z,11Z,14Z)) (View full structure)

m/zIon DescriptionStructure (click to enlarge)
830.5836Precursor ion [M.chloride]-
780.5913Loss of CH3 and chloride from precursor ion
709.5178Loss of choline and chloride from precursor ion
438.2990Loss of sn2 acyl chain as ketene (RCH=C=O), CH3 and chloride from precursor ion
420.2884Neutral loss of sn2 RCOOH group, loss of CH3 and chloride from precursor ion
359.2956sn2 RCOO- ion
349.2149Loss of choline, chloride and neutral loss of sn2 RCOOH group from precursor ion
315.3057Loss of CO2 from sn2 RCOO- ion (PUFA)
224.0693Glycerophosphocholine with loss of CH3 and H2O
168.0431Phosphocholine with loss of CH3
152.9958Glycerol-3-phosphate ion with loss of H2O
96.9696H2PO4- ion (from phosphate)
78.9591PO3- ion (from phosphate)
Note: Structures of product ions may represent one of a number of possible isobaric molecules in some cases