Commonly occurring product ions for PI(12:0/4:0) (View full structure)
| m/z | Ion Description | Structure (click to enlarge) |
|---|---|---|
| 585.2682 | Precursor ion [M-H]- |  |
| 515.2263 | Loss of sn2 acyl chain as ketene (RCH=C=O) from [M-H]- |  |
| 497.2157 | Neutral loss of sn2 RCOOH group from [M-H]- |  |
| 423.2153 | Loss of inositol from [M-H]- |  |
| 403.1011 | Loss of sn1 acyl chain as ketene (RCH=C=O) from [M-H]- |  |
| 385.0905 | Neutral loss of sn1 RCOOH group from [M-H]- |  |
| 353.1735 | Loss of sn2 acyl chain as ketene (RCH=C=O) and inositol from [M-H]- |  |
| 335.1629 | Neutral loss of sn2 RCOOH group and inositol from [M-H]- |  |
| 315.0487 | Glycerophosphoinositol -H2O |  |
| 297.0381 | Glycerophosphoinositol -2H2O |  |
| 259.0225 | Inositol phosphate ion |  |
| 241.0483 | Loss of sn1 acyl chain as ketene (RCH=C=O) and inositol from [M-H]- |  |
| 241.0119 | Inositol phosphate ion - H2O |  |
| 223.0377 | Neutral loss of sn1 RCOOH group and inositol from [M-H]- |  |
| 223.0013 | Inositol phosphate ion - 2 H2O |  |
| 199.1704 | sn1 RCOO- ion |  |
| 152.9958 | Glycerol-3-phosphate ion with loss of H2O |  |
| 96.9696 | H2PO4- ion (from phosphate) |  |
| 87.0452 | sn2 RCOO- ion |  |
| 78.9591 | PO3- ion (from phosphate) |  |